1-PROPYNYLMAGNESIUM BROMIDE

Basic information

  • Product Name:1-PROPYNYLMAGNESIUM BROMIDE
  • CasNo.:16466-97-0
  • MF:C3H3BrMg
  • MW:143.266

Physical and Chemical Properties

  • Purity:99%
  • Boiling Point:53.5 °C(Solv: methanol (67-56-1))
  • Packing:
  • Throughput:
Inquiry

Product Details

CasNo: 16466-97-0

MF: C3H3BrMg

Chinese Manufacturer Supply High Purity 99% Pure 16466-97-0 with Efficient Delivery

  • Molecular Formula:C3H3BrMg
  • Molecular Weight:143.266
  • Melting Point:53.5 °C(Solv: methanol (67-56-1)) 
  • Boiling Point:65-67 °C  
  • Flash Point:<−30 °F  
  • PSA:0.00000 
  • Density:0.941 g/mL at 25 °C  
  • LogP:1.36210 

1-PROPYNYLMAGNESIUM BROMIDE(Cas 16466-97-0) Usage

InChI:InChI=1/C3H2Br.Mg/c1-2-3-4;/h3H2;/q;+1/rC3H2BrMg/c4-2-1-3-5/h2H2/q+1

16466-97-0 Relevant articles

Palladium(II)-catalyzed dicarboxymethylation of chiral allylic alcohols: Chirality transfer affording optically active diesters containing three contiguous chiral centers

Hamed, Othman,Henry, Patrick M.,Becker, Daniel P.

supporting information; experimental part, p. 3514 - 3517 (2010/09/05)

This manuscript describes the extension ...

Synthesis of 9- and 10-membered rings by the intramolecular Michael addition of malonate on enone and ynone

Deslongchamps, Pierre,Roy, Bernard L.

, p. 2068 - 2075 (2007/10/02)

The base-catalysed (Cs2CO3 in THF/DMF) i...

Poly(dimethylsilmethylene) methylacetylene compound and a method for the preparation thereof

-

, (2008/06/13)

The invention provides a novel organosil...

Asymmetric synthesis of optically active compounds

-

, (2008/06/13)

Asymmetric synthesis of optically active...

16466-97-0 Process route

ethyl bromide
74-96-4

ethyl bromide

ammonium chloride

ammonium chloride

prop-1-yne
74-99-7

prop-1-yne

1-propynylmagnesium bromide
16466-97-0,13254-27-8

1-propynylmagnesium bromide

Conditions
Conditions Yield
With magnesium; In diethyl ether; water;
 
prop-1-yne
74-99-7

prop-1-yne

1-propynylmagnesium bromide
16466-97-0,13254-27-8

1-propynylmagnesium bromide

Conditions
Conditions Yield
With ethylmagnesium bromide;
 
With ethylmagnesium bromide; In tetrahydrofuran; at -78 - 40 ℃;
 
 
 

16466-97-0 Upstream products

  • 925-90-6
    925-90-6

    ethylmagnesium bromide

  • 74-99-7
    74-99-7

    prop-1-yne

  • 74-96-4
    74-96-4

    ethyl bromide

16466-97-0 Downstream products

  • 10229-10-4
    10229-10-4

    pent-3-yn-1-ol

  • 63124-68-5
    63124-68-5

    (E)-1-phenyl-1-hexen-4-yn-3-ol

  • 184577-40-0
    184577-40-0

    (+/-)-1-phenylhex-4-yn-3-ol

  • 16272-82-5
    16272-82-5

    1-Phenyl-1,4-hexadiyn-3-ol