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Allylmagnesium chloride

Basic information

  • Product Name:Allylmagnesium chloride
  • CasNo.:2622-05-1
  • MF:C3H5ClMg
  • MW:100.831

Physical and Chemical Properties

  • Purity:99%
  • Boiling Point:-21°C
  • Packing:clear tan to brown, amber, dark grey, dark green
  • Throughput:
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Product Details

CasNo： 2622-05-1

MF： C3H5ClMg

Appearance： clear tan to brown, amber, dark grey, dark green

Quality Manufacturer Supply High Purity 99% 2622-05-1, Sale Allylmagnesium chloride with Competitive Price

  • Molecular Formula:C3H5ClMg
  • Molecular Weight:100.831
  • Appearance/Colour:clear tan to brown, amber, dark grey, dark green 
  • Melting Point:-21°C 
  • Boiling Point:66°C 
  • Flash Point:1 °F  
  • PSA：0.00000 
  • Density:0.995 g/mL at 25 °C  
  • LogP:1.82950 

Allylmagnesium chloride(Cas 2622-05-1) Usage

Chemical Properties

clear tan to brown, amber, dark grey, dark green

Uses

Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.Grignard-reactions: reagent for the introduction of the allyl group.

Application

Used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins.

Precautions

It reacts violently with water.Air & moisture sensitive. Stable under recommended storage conditions.

InChI:InChI=1/C3H5.ClH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1/rC3H5Mg.ClH/c1-2-3-4;/h2H,1,3H2;1H/q+1;/p-1

2622-05-1 Relevant articles

Chemistry of fluorinated vinamidinium salts: Novel reactions of β-trifluoromethyl vinamidinium salt with Grignard reagents

Yamanaka, Hiroki,Uegaki, Tomonori,Ishihara, Takashi,Kubota, Toshio,Gupton, John T.

, p. 101 - 108 (1999)

β-Trifluoromethyl vinamidinium salt 1 re...

Scalable Continuous Synthesis of Grignard Reagents from in Situ-Activated Magnesium Metal

Deitmann, Eva,G?ssl, Lars,Hofmann, Christian,L?b, Patrick,Menges-Flanagan, Gabriele

, p. 315 - 321 (2020/03/10)

The continuous synthesis of Grignard rea...

PROCESS FOR PRODUCING PHOSPHONIUM BORATE COMPOUND, NOVEL PHOSPHONIUM BORATE COMPOUND, AND METHOD OF USING THE SAME

-

Page/Page column 76-77, (2008/06/13)

The invention relates to a phosphonium b...

2622-05-1 Process route

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

propene
187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4

propene

1,5-Hexadien
592-42-7

1,5-Hexadien

2-methylanthracene
613-12-7

2-methylanthracene

allylmagnesium bromide
2622-05-1

allylmagnesium bromide

Conditions
Conditions Yield
With magnesium 2-methylanthracene * 3 THF; In tetrahydrofuran; for 27h; Yield given. Yields of byproduct given; Ambient temperature;
 
9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium
86901-19-1

9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

anthracene
120-12-7

anthracene

9-(2-propenyl)-9,10-dihydroanthracene
84332-59-2

9-(2-propenyl)-9,10-dihydroanthracene

allylmagnesium bromide
2622-05-1

allylmagnesium bromide

2-Allyl-1,2-dihydro-anthracene
126695-01-0

2-Allyl-1,2-dihydro-anthracene

Conditions
Conditions Yield
In tetrahydrofuran; at -78 ℃; for 12h; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
 

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