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CasNo： 676-58-4
MF： CH3 Cl Mg
Appearance： dark brown solution
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Hazard |
Flammable, dangerous fire and explosionrisk. |
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General Description |
Methylmagnesium chloride is a Grignard reagent that exhibits higher reactivity toward carbonyl groups compared to dimethylmagnesium, as demonstrated in reactions with various carbonyl compounds. It is commonly used in organometallic reactions, such as cross-coupling and β-fluoride elimination processes, where it serves as a methylating agent or enhances reaction efficiency. Its reactivity is influenced by solvent choice and the presence of other organometallic species, making it a versatile reagent in synthetic chemistry. |
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Definition |
ChEBI: Methylmagnesium chloride is an alkylmagnesium halide and a one-carbon compound. available as a solutionin tetrahydrofuran. |
InChI:InChI=1/CH3.ClH.Mg/h1H3;1H;/q;;+1/p-1/rCH3Mg.ClH/c1-2;/h1H3;1H/q+1;/p-1
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methylene chloride
methylmagnesium chloride
| Conditions | Yield |
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With magnesium; In tetrahydrofuran;
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With magnesium; In solid matrix; at -258.2 ℃;
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With magnesium; lithium chloride; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;
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With iodine; magnesium; In dibutyl ether; at 40 ℃; for 1h; Solvent; Inert atmosphere;
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methylene chloride
methylmagnesium chloride
| Conditions | Yield |
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With diethyl ether;
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methylene chloride
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