What is the 1-PROPYNYLMAGNESIUM BROMIDE?

1-PROPYNYLMAGNESIUM BROMIDE is , while it's Molecular Formula is C 3 H 3 BrMg. 1-Propynylmagnesium Bromide Solution is a useful research reagent for chemical and organic transformations. It acts as a reagent in the synthesis of lasonolides a novel polyketides with biological activity in vitro against a variety of cancer cell lines.

What is the CAS number for 1-PROPYNYLMAGNESIUM BROMIDE?

The CAS number of 1-PROPYNYLMAGNESIUM BROMIDE is 16466-97-0.

1-PROPYNYLMAGNESIUM BROMIDE

Q: What is 1-PROPYNYLMAGNESIUM BROMIDE (16466-97-0) used for?

InChI:InChI=1/C3H2Br.Mg/c1-2-3-4;/h3H2;/q;+1/rC3H2BrMg/c4-2-1-3-5/h2H2/q+1

Basic information

Product Name:1-PROPYNYLMAGNESIUM BROMIDE
CasNo.:16466-97-0
MF:C₃H₃BrMg
MW:143.266

Physical and Chemical Properties

Purity:99%
Boiling Point:53.5 °C(Solv: methanol (67-56-1))
Packing:
Throughput:

Inquiry

Product Details

CasNo： 16466-97-0

MF： C₃H₃BrMg

Chinese Manufacturer Supply High Purity 99% Pure 1-propynylmagnesium bromide 16466-97-0 with Efficient Delivery

Molecular Formula:C₃H₃BrMg
Molecular Weight:143.266
Melting Point:53.5 °C(Solv: methanol (67-56-1))
Boiling Point:65-67 °C
Flash Point:<−30 °F
PSA：0.00000
Density:0.941 g/mL at 25 °C
LogP:1.36210

1-propynylmagnesium bromide (Cas 16466-97-0) Usage

Uses	1-Propynylmagnesium bromide is a research reagent used in chemical and organic transformations. It's also used in chemical analysis and solution deposition. Preparation of hydroxy enynes which underwent gold(I)-catalyzed benzannulation leading to tetrahydronaphthalenes.

InChI:InChI=1/C3H2Br.Mg/c1-2-3-4;/h3H2;/q;+1/rC3H2BrMg/c4-2-1-3-5/h2H2/q+1

16466-97-0 Relevant articles

Palladium(II)-catalyzed dicarboxymethylation of chiral allylic alcohols: Chirality transfer affording optically active diesters containing three contiguous chiral centers

Hamed, Othman,Henry, Patrick M.,Becker, Daniel P.

supporting information; experimental part, p. 3514 - 3517 (2010/09/05)

This manuscript describes the extension ...

Practical synthesis of (E)- and (Z)-2-silyl-3-penten-1-ols with high enantiopurity

Koichiro Fukuda a, Masaaki Miyashita b, Keiji Tanino a

, Tetrahedron Letters Volume 51, Issue 34, 25 August 2010, Pages 4523-4525

The optically pure (E)-allylsilane was synthesized from commercially available (R)-3-butyn-2-ol in five steps involving hydrozirconation followed by alkylation of the resulting alkenylmetal with BnOCH2Cl. On the other hand, both enantiomers of the corresponding (Z)-allylsilane were prepared from commercially available dimethylphenylvinylsilane through epoxidation, the regioselective epoxide-opening reaction with 1-propynylmagnesium bromide, and the subsequent optical resolution using a lipase.